Search Results

The modern diesel engine is used around the world to power applications as diverse as passenger cars, heavy-duty trucks, electrical power generators, ships, locomotives, agricultural and industrial equipment. The success of the diesel engine results from its unique combination of fuel economy, durability, reliability and affordability - which drive the lowest total cost of ownership. The diesel engine has been developed to meet the most demanding on-highway emission standards, through the introduction of advanced technologies such as: electronic controls, high pressure fuel injection, and cooled exhaust gas recirculation. The standards to be introduced in the U.S. in 2007 will see the introduction of the Clean Diesel which will achieve near-zero NOx and particulate emissions, while retaining the customer values outlined above.

A heavy-duty compression ignition engine using EGR and pilot-ignited directly injected natural gas fueling was calibrated for low NOx emissions. A Cummins ISX engine using cooled EGR was fitted with a Westport HPDI™ fuel system and an oxidation catalyst. The base engine hardware was modified to increase EGR rates (up to 40%). The engine, rated at 336 kW (450 hp) and 2236Nm (1650 ft-lbs), was calibrated and tested over steady state and transient test cycles. Steady state testing over the ESC 13-mode test cycle resulted in weighted composite NOx emissions of 0.36 g/bhp-hr and particulate matter emissions of 0.04 g/bhp-hr. Transient testing over the US EPA specified FTP cycle resulted in average NOx emissions of 0.6 g/bhp-hr and PM emissions of 0.03 g/bhp-hr.

Global emission legislations for diesel engines are becoming increasingly stringent. While the exhaust gas composition requirements for prior iterations of emission legislation could be met with improvements in the engine's combustion process, the next issue of European, North American and Japanese emission limits greater than 2005 will require more rigorous measures, mainly employment of exhaust gas aftertreatment systems. As a result, many American diesel OEMs are considering NOx adsorbers as a means to achieve 2007+ emission standards. Since the efficacy of a NOx adsorber over its lifetime is significantly affected by sulfur (“sulfur poisoning”), forthcoming reductions in diesel fuel sulfur (down to 15 ppm), have raised industry concerns regarding compatibility and possible poisoning effects of sulfur from the lubricant.

Stoichiometric natural gas engines with three-way catalysts emit less NOx and CH4 due to their higher efficiency compared to lean-burn natural gas engines. Although hydrothermal aging of three-way catalysts has been extensively studied, a deeper understanding beyond hydrothermal aging is needed to explain real-world performance, especially for natural gas engines with near-zero NOx emissions. In this investigation, field-aged three-way catalysts were characterized to identify the contribution of chemical aging to their overall performance. It was found that the sulfur species on the field-aged TWCs were entirely distributed along the catalyst length, showing a decreasing trend, whereas phosphorous contamination was mainly observed at the inlet section of the three-way catalysts, and the phosphorous concentration declined sharply along the axial length.

An axisymmetric finite element model is generated to simulate the windshield glass damage propagation subjected to impact loading of a flying object. The windshield glass consists of two glass outer layers laminated by a thin poly-vinyl butyral (PVB) layer. The constitutive behavior of the glass layers is simulated using brittle damage mechanics model with linear damage evolution. The PVB layer is modeled with linear viscoelastic solid. The model is used to predict and examine through-thickness damage evolution patterns on different glass surfaces and cracking patterns for different windshield designs such as variations in thickness and curvatures.

This paper describes a method for predicting structural failure probabilities for automotive windshields. The predictive model is supported by the data from strength tests performed on specimens of automotive glass. Evaluations of stresses can be based on finite element calculations, or measurements of the residual stresses that arise from fabrication. Failure probabilities for each subregion of a windshield are estimated from the local state of stress, the surface area or length (for edge elements) of the subregion, and statistical distributions of glass strengths. Example calculations are presented that show the relative contributions of edge stresses, surface stresses and residual stresses to calculated failure probabilities.

This paper presents the strength data for conventional automotive windshields in both the new and used conditions. More specifically, the biaxial strength of outer surface of curved and symmetrically laminated windshield, measured in biaxial flexure, is reported. The relative contributions of inplane membrane stress, which can be significant for new windshields, and bending stress are quantified with the aid of strain gauge rosettes mounted on both the outer and inner surfaces of windshield. The strength distribution for new and used windshields, based on Weibull distribution function, is found to be multimodal indicating more than one family of surface flaws. Depending on handling damage during manufacturing, assembly and installation processes, the low strength region of new windshields can approach that of used windshields with 50,000+ road miles!

Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system.

With new legislation and federal regulation for vehicle emission levels, automotive and truck manufacturers have been prompted to focus on emission control technologies that limit the level of exhaust pollutants. One of the primary pollutants, especially from diesel engines, is oxides of nitrogen (NOx). One possible solution to this pollution challenge is to design a more efficient internal combustion engine, which would require better engine operating parameter controls. However, there are limitations associated with such tight engine management. This need has led researchers and engineers to focus on the development of exhaust aftertreatment devices that will reduce NOx emissions with current diesel engines. An optimum aftertreatment device must be unaffected by exhaust-gas impurity poisoning such as sulfur products, and must have minimal impact on vehicle operations and fuel economy.

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO2. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 20% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K, with the highest activity observed at 773K. Examination of this large temperature window has shown that the optimum C1:NOx ratio changes with temperature.

NOx reduction under simulated lean burn conditions was studied using a non-thermal plasma in combination with zeolite and alumina catalysts. The influence of temperature and plasma treatment on the catalytic performance was investigated. Zeolite catalyst B showed high activity in the 150-300°C temperature region. Alumina Catalyst D was most active at temperatures higher than 250°C. In addition, the alumina catalyst was effective in oxidation of aldehydes formed during plasma treatment of the reaction mixture. When the reaction was carried out over a catalyst bed consisting of separate layers of the zeolite and alumina catalysts, the catalyst temperature range for significant NOx reduction was expanded to 150-500°C.

Effective control of exhaust emissions from modern diesel engines requires the use of aftertreatment systems. Elevated aftertreatment component temperatures are required for engine-out emissions reductions to acceptable tailpipe limits. Maintaining elevated aftertreatment components temperatures is particularly problematic during prolonged low speed, low load operation of the engine (i.e. idle, creep, stop and go traffic), on account of low engine-outlet temperatures during these operating conditions. Conventional techniques to achieve elevated aftertreatment component temperatures include delayed fuel injections and over-squeezing the turbocharger, both of which result in a significant fuel consumption penalty. Cylinder deactivation (CDA) has been studied as a candidate strategy to maintain favorable aftertreatment temperatures, in a fuel efficient manner, via reduced airflow through the engine.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

NOx reduction efficiency under simulated lean burn conditions is examined for a non-thermal plasma in combination with borosilicate glass, alumina, titania, Cu-ZSM-5 and Na-ZSM-5. The non-thermal plasma alone or with a packed bed of borosilicate glass beads converts NO to NO2 and partially oxidizes hydrocarbons. Alumina and Na-ZSM-5 reduce a maximum of 40% and 50% of NOx respectively; however, the energy cost is high for Na- ZSM-5. Cu-ZSM-5 converts less than 20% with a very high energy consumption. The anatase form of titania reduces up to 35% of NOx at a relatively high energy consumption (150J/L) when the catalyst is contained in the plasma region, but does not show any appreciable conversion when placed downstream from the reactor. This phenomenon is explained by photo-activation of anatase in the plasma.

One scenario for reducing engine out NOx in a spark ignition engine is to introduce small amounts of supplemental hydrogen to the combustion process. The supplemental hydrogen enables a gasoline engine to run lean where NOx emissions are significantly reduced and engine efficiency is increased relative to stoichiometric operation. This paper reports on a mass and energy balance model that has been developed to evaluate the overall system efficiencies of a thermal reformer-heat exchanger system capable of delivering hydrogen to the air intake of a gasoline engine. The mass and energy balance model is utilized to evaluate the conditions where energy losses associated with fuel reformation may be offset by increases in engine efficiencies.

Accumulation of lubricant and fuel derived ash in the diesel particulate filter (DPF) during vehicle operation results in a significant increase of pressure drop across the after-treatment system leading to loss of fuel economy and reduced soot storage capacity over time. Under certain operating conditions, the accumulated ash and/or soot cake layer can collapse resulting in ash deposits upstream from the typical ash plug section, henceforth termed mid-channel ash deposits. In addition, ash particles can bond (either physically or chemically) with neighboring particles resulting in formation of bridges across the channels that effectively block access to the remainder of the channel for the incoming exhaust gas stream. This phenomenon creates serious long-term durability issues for the DPF, which often must be replaced. Mid-channel deposits and ash bridges are extremely difficult to remove from the channels as they often sinter to the substrate.

Optimizing the performance of the aftertreatment system used on heavy duty diesel engines requires a thorough understanding of the operational characteristics of the individual components. Within this, understanding the performance of the catalyzed particulate filter (CPF), and the development of an accurate CPF model, requires knowledge of the particulate matter (PM) distribution throughout the substrate. Experimental measurements of the PM distribution provide the detailed interactions of PM loading, passive oxidation, and active regeneration. Recently, a terahertz wave scanner has been developed that can non-destructively measure the three dimensional (3D) PM distribution. To enable quantitative comparisons of the PM distributions collected under different operational conditions, it is beneficial if the results can be discussed in terms of the axial, radial, and angular directions.

An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.

The present study examines the impact of using low thermal mass (LTM) turbine housing designs on the transient characteristics of the turbine outlet temperature for a light-duty diesel standard certification cycle (FTP75). For a controlled exhaust flow, the turbine outlet temperature will directly determine the impact on an aftertreatment system warm-up from a cold state, typical of engine-off and engine idling conditions. The performance of the aftertreatment system such as a Selective Catalytic Reduction (SCR) system is highly dependent on how quickly it warms up to its desirable temperature to be able to convert the harmful oxides of Nitrogen (NOx) to gaseous Nitrogen. Previous works have focused on mostly insulating the exhaust manifold and turbine housing to conserve the heat going into the aftertreatment system. The use of LTM turbine housing has not been previously considered as a means for addressing this requirement.

Three-way catalysts have been used in a variety of stoichiometric natural gas engines for emission control. During real-world operation, these catalysts have experienced a large number of temporary and permanent deactivations including thermal aging and chemical contamination. Thermal aging is typically induced either by high engine-out exhaust temperatures or the reaction exotherm generated on the catalysts. Chemical contamination originates from various inorganic species such as Phosphorous (P) and Sulfur (S) that contain in engine fluids, which can poison and/or mask the catalyst active components. Such deactivations are quite difficult to simulate under laboratory conditions, due to the fact that multiple deactivation modes may occur at the same time in the real-world operations. In this work, a set of field-aged TWCs has been analyzed through detailed laboratory research in order to identify and quantify the real-world aging mechanisms.